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On the nucleophilic tele-substitution of dichloropyrazines by metallated dithianes

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Date
2006
ICR Author
Torr, Jane
Large, Jonathan
McDonald, Edward
Author
McDonald, T
Type
Journal Article
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Abstract
On the nucleophilic tele-substitution of dichloropyrazines by metallated dithianes The reaction of dichloropyrazines with a dithiane anion gave isomers of the expected formylated chloropyrazines after deprotection with methyl iodide. A tele-substitution mechanism accounts for these observations and is supported by deuterium labelling studies. (c) 2005 Elsevier Ltd. All rights reserved.
URI
https://repository.icr.ac.uk/handle/internal/1906
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Subject
pyrazines dithianes tele-substitution metallation Directed metalation diazines pyridines pyrazines benzodiazines pyridazines pyrimidines carbolines quinolines azines
Language
eng
License start date
2006
Citation
TETRAHEDRON LETTERS, 2006, 47 (1), pp. 31 - 34

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